耗材描述

• 分子式 (C₆H₁₁)₂PCl
• 分子量232.73
• Beilstein号 16(4)968
• EC号
• MDL号 MFCD00014294
• PubChem编号

属性

沸点	165 °C/12 mmHg
折光率	1.533
敏感性	对空气和湿度敏感
溶解性	Reacts violently with water
存贮条件	充氩保存
密度	1.0540

描述

应用

Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of: · 1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis?Arbuzov type rearrangements. · 1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS. It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions.

别名

二-环己基氯化膦;二环己氯化膦;二环己氯膦;氯代二环己基膦;二环己基次膦酰氯;二环己基氯膦;Dicyclohexylchlorophosphine; Dicyclohexylphosphine chloride; Dicyclohexylphosphinous chloride

Reaxys-RN	956672
信号词	Danger
危害声明	H314
警示性声明	P280-P305 + P351 + P338-P310
个人防护设备	Faceshields， full-face respirator (US)， Gloves， Goggles， multi-purpose combination respirator cartridge (US)， type ABEK (EN14387) respirator filter
WGK德国	3
闪点（摄氏）	>110°

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