β-溴苯乙烯 (顺反异构体混合物)
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分子式 C8H7Br 分子量183.05 Beilstein号 EC号 MDL号 MFCD00000185 PubChem编号 属性 沸点 110-112 °C 熔点 7 °C 存贮条件 贮存温度2-8°C 密度 1.4270 //deco
货号 | CAS号 | 价格 | 操作 |
---|---|---|---|
B152003-5g | 103-64-0 | ¥159.00 | 询底价 |
耗材描述
- 分子式 C8H7Br
- 分子量183.05
- Beilstein号
- EC号
- MDL号 MFCD00000185
- PubChem编号
属性
沸点 | 110-112 °C |
熔点 | 7 °C |
存贮条件 | 贮存温度2-8°C |
密度 | 1.4270 |
描述
应用 | β-Bromostyrene was used in the one-pot method for the preparation of cinnamonitriles. It was also used in the preparation of pure ethyl Z- and E-α,α-difluoro-4-phenyl-3-butenoate and 1,3-diphenyl-1-butene. It may be used in the synthesis of β-tert-butylstyrene via cross coupling reaction with tert-butylmagnesium chloride in the presence of dichloro[1,1′-bis(diphenylphosphino)ferrocene]nickel(II) catalyst. It may also be used to prepare γ-but-2-enolactone by reacting with nickel carbonyl in the presence of alkynes. |
产品介绍 | β-Bromostyrene is an α,β-unsaturated aromatic halide. It can be synthesized by catalytic Hunsdiecker reaction (CHR) of cinnamic acid. It is commonly utilized as a precursor for preparing substituted alkenes, corresponding acetylenes and also in the total synthesis of natural compounds and antibiotics. |
别名 | 2-溴乙烯基苯 (顺反混合物);溴代苏合香烯 (顺反混合物);1-溴-2-苯乙烯 (顺反混合物);beta-Bromostyrene |
Reaxys-RN | 1903529 |
信号词 | Warning |
危害声明 | H302 |
个人防护设备 | Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
RTECS | WL3850000 |
WGK德国 | 3 |
闪点(摄氏) | 120°C |
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