| 应用 |
Reagent Used for Reductive silylation and the preparation of trifluoro- and difluoromethylsilanes by reductive coupling of fluoromethyl sulfones, sulfoxides and sulfides with chlorosilanes;Fluoroalkylation/chloroalkylation of α,β-enones, arynes, acetylenic ketones and other Michael acceptors;Difluoromethylation of primary alkyl halides via nucleophilic substitution-reductive desulfonylation.
Reagent used in Preparation of α-difluoromethyl amines via stereoselective (phenylsulfonyl)difluoromethylation of chiral sulfinyl aldimines;Anti-difluoropropanediols via potassium tert-butoxide-catalyzed difluoromethylenation of aldehydes;β-difluoromethylated and β-difluoromethylenated alcohols and amines by regioselective nucleophilic difluoromethylation of 1,2-cyclic sulfates and sulfamidates;Difluoroalkenes from alkyl halides via nucleophilic substitution-elimination; Difluoromethyl alcohol derivatives from enolizable and non-enolizable carbonyl compounds using nucleophilic phenylsulfonyldi |
