中文名:6,6-二甲基富烯
英文名:6,6-Dimethylfulvene
中文别名:6,6-二甲基富烯|5-(1-甲基亚乙基)-1,3-环戊二烯, 5-异亚丙基-1,3-环戊二烯|5-(二甲基亚甲基)-1,3-环戊二烯
英文别名:6,6-Dimethylfulvene|2175-91-9|5-(propan-2-ylidene)cyclopenta-1,3-diene|5-propan-2-ylidenecyclopenta-1,3-diene|1,3-Cyclopentadiene, 5-(1-methylethylidene)-|Dimethylfulvene|5-Isopropylidene-1,3-cyclopentadiene|6,6'-Dimethylfulvene|Isopropylidenecyclopentadi
纯度:95%
货号:D168651
Cas号:2175-91-9
存储温度:-20°C储存,充氩
产品介绍:
6,6-Dimethylfulvene [5-(1-methylethylidene)-1,3-cyclopentadiene] is a nonaromatic carbocyclic analog of isopropylbenzene.6,6-Dimethylfulvene reacts with 2,2-bis(trifluoromethyl)-1,1-dicyanoethylene (BTF; 1) to afford the expected Diels-Alder cycloadduct, 7-(1-methylethylidene)-3,3-bis(trifluoromethyl)bicyclo[2.2.1]hept-5-ene-2,2-dicarbonitrile.Metal-free hydrogenation of 6,6-dimethylfulvene via frustrated Lewis pair (FLP) mediated triple domino reaction has been reported.The biotransformation of 6,6-dimethylfulvene by Pseudomonas putida RE213 has been studied.Cycloaddition of 6,6-dimethylfulvene with benzynes has been reported. 6,6-Dimethylfulvene may be employed in the following studies: · One-pot synthesis of ansa-metallocenes. · Synthesis of endo and exo-adducts with maleic anhydride. · Synthesis of fulvenols or the corresponding trimethylsilyl ethers
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