中文名：4,4,4-三氟乙酰乙酸乙酯

英文名：Ethyl 4,4,4-trifluoroacetoacetate

中文别名：4,4,4-三氟乙酰乙酸乙酯|三氟乙酰乙酸乙酯|ETFAA

英文别名：Ethyl 4,4,4-trifluoroacetoacetate|372-31-6|Ethyl 4,4,4-trifluoro-3-oxobutanoate|Ethyl trifluoroacetoacetate|4,4,4-trifluoro-3-oxobutanoic acid ethyl ester|Ethyl (trifluoroacetyl)acetate|Butanoic acid, 4,4,4-trifluoro-3-oxo-, ethyl ester|ETFAA|4,4,4-Triflu

纯度：98%

货号：E109508

Cas号：372-31-6

存储温度：充氩

产品介绍：

溶于乙醇、醚、苯等溶剂。水中溶解度:10 g/l (20°C)。合成含氟杂环医药和农药的重要中间体，有机合成砌块。

Ethyl 4,4,4-trifluoroacetoacetate (ETFAA) is a general reagent to synthesize enantiopure trifluoromethyl-functionalized products. Applications include:

• Synthesis of (S)- and (R)-α-trifluoromethyl-aspartic acid and α- trifluoromethyl-serine from chiral CF3-oxazolidines, which is derived from ETFAA.

• Enantiopure synthesis of trifluoromethyl-β-amino acid derivatives.

• Synthesis of (2R)-2-trifluoromethyl-2-carboxyazetidine, (R)- and (S)-trifluoromethylhomoserines from oxazolidine intermediate obtained by condensing (R)-phenylglycinol with ETFAA.

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