T111845-1g1,1-硫代羰基二咪唑
¥
99.00
- 阿拉丁
- 生产商
- T111845-1g
- 现货
- 全国
规格 |
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耗材描述
- 分子式 C7H6N4S
- 分子量178.21
- Beilstein号 609349
- EC号 228-183-4
- MDL号 MFCD00005289
- PubChem编号 24889110
属性
熔点 | 97-105°C |
敏感性 | 对湿度敏感 |
溶解性 | Soluble in terahydrofuran, toluene and dichloromethane. |
存贮条件 | 储存温度 2-8°C,充氩保存 |
密度 | 1.3900 |
描述
应用 |
合成硫代酰胺的试剂;从醇中制备硫代甲酸酯,期间要和Bu3SnH-AIBN3剧烈反应。 · 1,1′-Thiocarbonyldiimidazole (TCDI) is generally used as a reagent to carry out the deoxygenation of vicinal diols by forming cyclic thionocarbonate in Corey-Winter alkene synthesis. · It is used as a reagent in the enantioselective total synthesis of (+)-hapalindole Q, 12-epi-fischerindole U and welwitindolinone A. · It is also used in the preparation of trithiocarbonates, xanthates, and dithiocarbamates as chain transfer agents for the reversible addition fragmentation chain transfer and macromolecular design (RAFT/ MADIX) polymerization. |
产品介绍 | 溶于水并分解。 |
别名 | 1,1'-硫羰基二咪唑;1-1'-巯基羧基二咪唑;N,N'-硫代羰基二咪唑;1,1-硫代羰基二咪唑;N,N'-硫羰基二咪唑;1,1'-Carbonothioylbis-1H-imidazole; 1,1'-Thiocarbonyldiimidazole; TCDI; 1,1'-Thiocarbonylbis(imidazole) |
Reaxys-RN | 609349 |
标识符号 |
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信号词 | Warning |
危害声明 | H315,H319 |
警示性声明 | P264,P280,P302+P350,P305+P351+P338,P332+P313,P337+P313,P362 |
个人防护设备 | Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter |
WGK德国 | 3 |
风险声明 (欧洲) | R22;R34; |
安全声明(欧洲) | S26;S36/37/39/;S45; |
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