T162479-25G&(叔丁基二甲基硅烷基)乙炔
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- T162479-25G
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规格 |
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耗材描述
- 分子式 C8H16Si
- 分子量140.30
- Beilstein号
- EC号
- MDL号 MFCD00191877
- PubChem编号
属性
沸点 | 116-117 °C |
折光率 | 1.451 |
敏感性 | 对湿度敏感 |
溶解性 | Sparingly soluble in water (0.043 g/L at 25°C). |
存贮条件 | 充氩保存 |
密度 | 0.7510 |
描述
应用 | (tert-Butyldimethylsilyl)acetylene may be used in the synthesis of β-alkynylketone[1] and β-alkynyl aldehydes. |
产品介绍 | (tert-Butyldimethylsilyl)acetylene is a bulky trialkylsilyl-protected alkyne. It participates in Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to afford synthetically useful unsymmetrical diynes. (tert-Butyldimethylsilyl)acetylene readily undergoes cross-dimerization reaction with various internal phenyl acetylenes in the presence of rhodium dimers and bidentate phosphine ligands to afford enynes. |
别名 | 叔丁基乙炔基二甲基硅烷;叔丁基二甲基硅烷乙炔;(tert-Butyl)ethynyldimethylsilane;tert-Butyldimethylsilylacetylene |
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