T104475-2.5kg三苯基膦
面议
- 阿拉丁
- 生产商
- T104475-2.5kg
- 现货
- 全国
规格 |
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耗材描述
- 分子式 C18H15P
- 分子量262.29
- Beilstein号 610776
- EC号 210-036-0
- MDL号 MFCD00003043
- PubChem编号
属性
沸点 | 377°C |
熔点 | 80.5°C |
敏感性 | 对光敏感 |
溶解性 | Soluble in ether, acetone, chloroform (50 mg/ml), and alcohol. Insoluble in water. |
存贮条件 | 充氮密封保存。 |
密度 | 1.1320 |
描述
应用 | 用于有机合成,聚合引发剂,抗菌素类药物氯洁霉素的原料,有机微量分析测定磷的标准样品。 |
产品介绍 | 无气味。摩擦能发光。易溶于乙醚,溶于氯仿、乙酸和苯,微溶于乙醇,几乎不溶于水。低毒,半数致死量(大鼠,经口)800mg/kg。有刺激性。 Rhodium and triphenylphosphine catalyst system has been used for the hydroformylation of soybean, safflower and linseed oils and their methyl esters. Polymer supported triphenylphosphine has been reported to efficiently catalyze the γ-addition of pronucleophiles to alkynoate. Triphenylphosphine reacts with hydrated ruthenium trichloride in methanol to afford [RuCl2(PPh3)4], [RuCl2(PPh3)3] and [RuCl3(PPh3)2CH3OH].It participates in the Heck reaction of 4-bromoanisole and ethyl acrylate in ionic liquids. |
别名 | 三苯膦;Phosphorustriphenyl |
Merck Index | 9743 |
标识符号 |
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信号词 | Warning |
危害声明 | H302,H317,H319,H411 |
警示性声明 | P273,P280,P305+P351+P338 |
个人防护设备 | dust mask type N95 (US),Eyeshields,Faceshields,Gloves |
RTECS | SZ3500000 |
WGK德国 | 2 |
闪点(摄氏) | (开杯)180℃ |
风险声明 (欧洲) | R22;R43;R53 |
安全声明(欧洲) | S26;S36/37/39;S61 |
危害码(欧洲) | Xn |
是否危化品 | 一般危化品 |
UN代码 | 3077 |
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